Xps Study of the Oxidation State of Uranium Dioxide

Authors

  • J. A. Lopez Department of Physics, University of Texas at El Paso, El Paso, Texas 79968, U.S.A
  • C. Diaz Moreno Department of Physics, University of Texas at El Paso, El Paso, Texas 79968, U.S.A.
  • J. Morillo Department of Chemistry, University of Texas at El Paso, El Paso, Texas 79968, U.S.A.
  • L. Echegoyen Department of Chemistry, University of Texas at El Paso, El Paso, Texas 79968, U.S.A.

DOI:

https://doi.org/10.15415/jnp.2017.51022

Keywords:

Uranium dioxide, XPS, Chemical shift, Oxidation states

Abstract

In this article we report an investigation of the oxidation state of uranium dioxide using X-Ray Photoelectron Spectroscopy, and by comparing to results obtained in previous studies. We find that uranium dioxide in powder appears to share its six valence electrons with the oxygen atoms to form crystalline UO3.

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References

Y.Q. An, A.J. Taylor, S.D. Conradson, S.A. Trugman, T. Durakiewicz, G. Rodriguez, Physical Review Letters. 106 (2011) 207402.

The Handbook of X-ray Photoelectron Spectroscopy, Physical Electronics, Inc., (2000) 6509 Flying Cloud Dr., Eden Prairie, MN 55344.

J. H. Liu, et al, J. Solid State Chemistry 182 (2009) 1105.

E. S. Ilton and P. S. Bagus, Surf. Interface Anal. 43 (2011) 1549.

P.S. Bagus, C.J. Nelin, and E.S. Ilton, J. Chem. Phys. 139 (2013) 244704

L.B. Skinner, C.J. Benmore, J.K.R. Weber, M.A. Williamson, A. Tamalonis, A. Hebden, T. Wiencek, O.L.G. Alderman, M. Guthrie, L. Leibowitz, J.B. Parise, Science, 346 (2014) 984.

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Published

2017-08-07

How to Cite

(1)
Lopez, J. A. .; Moreno, C. D.; Morillo, J. .; Echegoyen, L. . Xps Study of the Oxidation State of Uranium Dioxide. J. Nucl. Phy. Mat. Sci. Rad. A. 2017, 5, 237-242.

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Articles